Design your own desktop with Xfce 4.4
Xfce is just as customizable as KDE or GNOME, so I set myself a goal: make Xubuntu look like Windows Vista. Why? Because I can.
Though you won’t be told how to achieve the exact same end result (Microsoft™©® most likely would not appreciate that), this guide provides comprehensive instructions helping you make Xubuntu look the way you want it to. In any case, I would certainly not recommend such a setup for someone new to Xubuntu. Xubuntu is different than Windows; making it look similar is only confusing.
Since Windows comes with a total of a mere one panel, I had to remove one of Xubuntu’s two default panels. This task was easily done using Xfce’s Panel Manager, which can be opened by right clicking empty space on a panel and selecting Customise Panel, or by opening Applications->Settings->Panel Manager.